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In April 2024, the Environmental Protection Agency (EPA) finalized  workplace protections under the Toxic Substances Control Act (TSCA) for methylene chloride to protect human health.

The regulation strives to reduce workers’ exposure to methylene chloride by banning the use and manufacturing of methylene chloride, except for a chosen limited use, such as a research lab.

Methylene chloride found in your work area that does not meet the exceptions or is no longer going to be used, will need to be disposed of (see the compliance guide) per guidance from Environmental Management

If your department plans to keep using Methylene chloride, sampling will need to be performed to ensure exposure limits are being met (see table 1).

More information about the Ruling as well as the banned use and exceptions to the rule can be found in the Compliance Guide.

 

Basic Facts about Methylene Chloride
  • It is colorless liquid and a volatile chemical with a sweet odor
  • Its name can appear as Methylene Chloride (MeCl) or Dichloromethane (DCM)
  • It is a solvent used in consumer and commercial applications, including adhesives and sealants.  Used in the automotive industry as a degreaser and cleaner.
  • Methylene chloride’s primary route of exposure is inhalation. Exposures can also occur through the skin, or ingested.
  • Employees exposed to methylene chloride are at increased risk of developing cancer, adverse effects on the heart, central nervous system and liver, and skin or eye irritation.

Steps for Complying with EPA Standard

Table 1: Steps for Complying with the EPA Standard for Non-Laboratory Workers


MeCl Steps for Compliance Flow Chart

 

                  Research Laboratory Usage 

                     Contact Research Safety

                   Or email: labsafety@uky.edu            

Dates to Complete EPA Requirements:

Table 2: EPA Requirements Due Dates
Action Item Due Date (to be completed by)
Publication of EPA’s regulation May 8, 2024
Initial Air Monitoring May 5, 2025
Exposure Limits and Dermal Protections August 1, 2025
Exposure Control Plan October 30, 2025
Periodic Monitoring 3 months to 5 years

Sampling

What is Industrial Hygiene's Method of Sampling?
  • Occupational Health and Safety will place a passive badge on employees to perform a process or tasks that contain methylene chloride.
  • The employee(s) will wear the badge for a minimum of 15 minutes.
  • The sample/s will then be sent to an accredited laboratory.
  • The Employee will be notified of their results, and the supervisor will be given the sampling report.
  • If the result is over the exposure limit, OHS will collaborate with the employee/supervisor to determine engineering controls. Once controls are in place, resampling will occur.  OHS will continue to periodically monitor. 

 

Will this cost the employee money?   

No, sampling will be provided for the employee at no cost. 

EPA Exposure Limits

The EPA exposure limits are divided into two exposure groups based on the sampling time.   An EPA STEL (short term exposure limit) is based on a 15-minute sample.   An ECEL (EPA existing chemical exposure limit) is based on an eight-hour workday.  The exposure limits are measured by parts per million, or ppm. 

Exposure Type  Exposure limit (ppm) Sampling time
ECEL 2 Greater than 15 minutes
EPA STEL 16 15 minutes

Results

The Industrial Hygiene Team has performed sampling for multiple operations on campus (table 4 and table 5).

 

Table 4: Methylene Chloride Sampling Results for an ECEL 8-hour Time Weighted Average
Operations Exposure control devices Result (ppm) Exposure Limit (ppm) ECEL
Glass Cleaning Chemical Fume Hood 0.940 2 ECEL
Column Chromatography Chemical Fume Hood *0.0310 to 1.9
Reduction Chemical Fume Hood 0.320
Pentacene Chemical Fume Hood 0.310
Dipeptide Chemical Fume Hood 0.330
Supervising Chemical Fume Hood 0.310
Column Chromatography Cleaning None 0.310
Thin-layer Chromatography Chemical Fume Hood 0.320

*A variety of Column Chromatography processes were sampled.  

 

Table 5: Methylene Chloride Sampling Results for a Short-Term Exposure Limit (STEL) of 15 minutes
Operation Exposure control devices Result (ppm) Exposure Limit (ppm) STEL
Column Chromatography Chemical Fume Hood *<10 to 3.20 16 STEL
Reduction Chemical Fume Hood 10.000
Pentacene Chemical Fume Hood 10.000
Dipeptide Chemical Fume Hood 10.000
*Agent Transfer Chemical Fume Hood 10.000
*Agent Transfer Chemical Fume Hood 10.000
Thin-layer Chromatography Chemical Fume Hood 10.000
*Agent Transfer None 10.000
Column Chromatography Preparation None 10.000

*A variety of similar processes were sampled.  

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