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Basic Facts about Methylene Chloride

Why the attention? 

In April 2024, the Environmental Protection Agency (EPA) finalized prohibitions and workplace protections under the Toxic Substances Control Act (TSCA) for methylene chloride to protect human health.

The regulation strives to reduce workers’ exposure to methylene chloride by banning the use and manufacturing, except for some limited use, such as a research lab.

Methylene chloride found in your work area, that does not meet the exceptions or is no longer wanted, will need to be disposed (see the compliance guide). Please contact Environmental Management, and fill out a ticket for disposal request.

If your department plans to keep using Methylene chloride, sampling will need to be performed to ensure exposure limits are being met (see table 1).

More information about the Ruling and on banned use and the exceptions to the rule can be found in the Compliance Guide.

 

 

Basic Facts about Methylene Chloride
What is it?  

A colorless liquid and a volatile chemical with a sweet odor.

 

What are other names?   

Dichloromethane or DCM.

 

What are the uses?   

A solvent used in consumer and commercial applications, including adhesives and sealants.  Used in the automotive industry as a degreaser and cleaner. 

 

How do exposures occur?  

Methylene chloride is primarily inhaled.  However, exposure can also occur through the skin, or ingested.  

 

What are the risks?  

Employees exposed to methylene chloride are at increased risk of developing cancer, adverse effects on the heart, central nervous system and liver, and skin or eye irritation. 

Steps for Complying with EPA Standard

Table 1: Steps for Complying with the EPA Standard

    Research Laboratory Usage

        Contact Research Safety

     Or email: labsafety@uky.edu  

  Nonlaboratory Usage
Step 1 Contact Occupational Health and Safety (OHS)
Step 2 Hazard Assessment to be performed by OHS
Step 3 Sampling will be scheduled and performed
Step 4 Results and the next steps will be given.
Step 5 Worker Protection Plan Created (OHS will assist as needed)
Step 6 Follow up sampling using EPA Guidelines

 

Dates to Complete EPA Requirements:

Table 2: Dates to Meet EPA Requirements

Action Item Date (to be completed by)
Publication of EPA’s regulation May 8, 2024
Initial Monitoring May 5, 2025
Exposure Limits and Dermal Protections August 1, 2025
Exposure Control Plan October 30, 2025
Periodic Monitoring 3 months to 5 years

 

Sampling

What is OHS's Method of Sampling?
  • Occupational Health and Safety will place a passive badge on employees to perform a process or tasks that contain methylene chloride.
  • The employee(s) will wear the badge for a minimum of 15 minutes. 
  •  The sample/s will then be sent to an accredited laboratory. 

    The Employee will be notified of their results, and the supervisor will be given the sampling report. 

 

Will this cost the employee money?   

No, sampling will be provided for the employee at no cost. 

 

 

The process/tasks have been sampled, what’s next?   

If results determine the result is over the exposure limit, OHS will collaborate with the employee/supervisor to determine controls. Once controls are in place, resampling will occur.  Periodic Monitoring will be continued based on results and EPA guidance.

 

Results

The EPA exposure limits are divided into two exposure groups depending on the sampling time.   An EPA STEL (short term exposure limit) is based on a 15-minute sample.   An ECEL (EPA existing chemical exposure limit) is based on an eight-hour workday.  Below is a chart showing the EPA exposure limits. The exposure limits are measured by parts per million, or ppm.

 

Exposure Type  Exposure limit (ppm) Sampling time
ECEL 2 Greater than 15 minutes
EPA STEL 16 15 minutes

 

Below are tables of the results of sampling that has been performed for different laboratory processes at the University of Kentucky. 

Table 4: Methylene Chloride Sampling results for an ECEL 8-hour Time Weighted Average

Operations Exposure control devices Result (ppm) Exposure Limit (ppm) ECEL
Glass cleaning CFH 0.940 2 ECEL
*Column chromatography CFH Range 1.9 to .0310
Reduction CFH 0.320
Pentacene CFH 0.310
Dipeptide CFH 0.330
Supervising CFH 0.310
Column chromatography cleaning None 0.310
Thin-layer chromatography CFH 0.320

*A variety of Column Chromatography processes were sampled.  

Table 5: Methylene Chloride Sampling results for a Short-Term Exposure Limit (STEL) of 15 minutes

Operation Exposure control devices Result (ppm) Exposure Limit (ppm) STEL
*Column chromatography CFH <10 to 3.20 16 STEL
Reduction CFH 10.000
Pentacene CFH 10.000
Dipeptide CFH 10.000
Agent transfer CFH 10.000
Agent transfer CFH 10.000
Thin-layer chromatography CFH 10.000
Agent transfer None 10.000
Column chromatography preparation None 10.000

*A variety of Column Chromatography processes were sampled.